Modulation of TADF and RTP in organic molecules optimizes optoelectronic properties through structural and environmental tuning. TADF is enhanced by minimizing ΔEST in D-A systems via steric twists and phenyl insertions, promoting rISC. RTP relies on rigid packing (H-bonding, halogen bonds) and heavy atoms (Br/I) to suppress non-radiative decay and boost ISC. Dual-emission materials align T1/T2 states, using internal/external halogens or donor engineering for balanced TADF/RTP, as in morpholine or phthalimide derivatives. These strategies yield high quantum yields and stimuli-responsive emissions for OLEDs and sensing.
Some idea of spectroscopy, organic name reactions
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